Cas-код 5- (2-гидроксиэтил) -4-метилтиазола Meatyï - 137-00-8.
Content analysis Toxicity Usage limit FEMA Chemical properties Application Preparation
Product Name: |
5-(2-Hydroxyethyl)-4-methylthiazole(Meaty) |
Synonyms: |
A875 Cell;1-(4-methyl-5-thiazolyl)ethanol;4-Methyl-5-thiazoleethanol, 98% 100ML;5-(2-HYDROXYETHYL)-4-METHYLTHIAZOLE FOR;Methyl-5-thiazoleetha;4- Methyl-5- thiazolealcohol;5-(2-Hydroxyethyl)-4-methylthiazole in stock Factory;4-Methyl-5-Hydroxyethyl Thiazole (Meaty, Beany & Milky) |
CAS: |
137-00-8 |
MF: |
C6H9NOS |
MW: |
143.21 |
EINECS: |
205-272-6 |
Product Categories: |
alcohol;Thiazole;Alkohols;thiazole Flavor |
Mol File: |
137-00-8.mol |
|
Melting point |
<25 °C |
Boiling point |
135 °C7 mm Hg(lit.) |
density |
1.196 g/mL at 25 °C(lit.) |
FEMA |
3204 | 4-METHYL-5-THIAZOLEETHANOL |
refractive index |
n20/D 1.550(lit.) |
Fp |
>230 °F |
storage temp. |
Store below +30°C. |
solubility |
alcohol: soluble(lit.) |
form |
liquid (clear, viscous) |
pka |
14.58±0.10(Predicted) |
color |
deep yellow |
Specific Gravity |
1.196 |
Odor |
meaty, roasted odor |
Sensitive |
Stench |
JECFA Number |
1031 |
Merck |
14,6126 |
BRN |
114249 |
InChIKey |
BKAWJIRCKVUVED-UHFFFAOYSA-N |
CAS DataBase Reference |
137-00-8(CAS DataBase Reference) |
NIST Chemistry Reference |
5-Thiazoleethanol, 4-methyl-(137-00-8) |
EPA Substance Registry System |
5-Thiazoleethanol, 4-methyl- (137-00-8) |
Hazard Codes |
Xi |
Risk Statements |
36/37/38 |
Safety Statements |
26-36-24/25-7/9 |
RIDADR |
UN 3334 |
WGK Germany |
3 |
F |
13 |
Hazard Note |
Irritant/Stench |
TSCA |
Yes |
HS Code |
29341000 |
Content analysis |
It was determined by gas chromatography (GT-10-4) using a nonpolar column method. |
Toxicity |
GRAS (FEMA) |
Usage limit FEMA |
soft drinks, cold drinks, candy, baked goods, jelly, pudding, jelly sugar, seasonings, meat products, meat soup, milk and dairy products as well as cereal product: 55.0mg/kg. |
Chemical properties |
It appears as colorless to pale yellow viscous oily liquid. The color will turn dark after being subject to long-term storage. It emit unpleasant thiophene compound odor with high dilution generating nut aroma. The boiling point is 103 ° C (133 Pa), or 135 ° C (933 Pa). It is easily soluble in water, soluble in ethanol, ether, benzene and chloroform. |
Application |
· Used as temporarily allowable food spices; · For nuts, dairy products, meat products, etc., as pharmaceutical intermediates; · Used for the deployment of chocolate, milk and nuts |
Preparation |
It is obtained from the reduction of 4-methyl thiazole 5-ethyl acetate reduction with lithium aluminum hydride. |
Description |
4-Methy 1-5-thiazoleethanol has the characteristic disagreeable odor of thiazole compounds. It is somewhat pleasant and nut-like on extreme dilution. It may be prepared by reduction of ethyl- 4-methylthiazole-5-acetate using LiAlH4; by condensation of thioformamide with bromoacetopropanol or with y,y-dichloro-y,ydiacetodipropyl ether. |
Chemical Properties |
4-Methyl-5-thiazoleethanol has a disagreeable odor typical of thiazole compounds; somewhat pleasant, reminiscent of beef and nut-like, on extreme dilution |
Chemical Properties |
Colorless to light yellow liqui |
Preparation |
By reduction of ethyl-4-methylthiazole-5-acetate using LiAlH4; by condensation of thioformamide with bromoacetopropanol or with γ, y-dichloro-γ,γ-diacetodipropyl ether |
Definition |
ChEBI: A 1,3-thiazole that is thiazole substituted by a methyl group at position 4 and a 2-hydroxyethyl group at position 5. |
Taste threshold values |
Taste characteristics at 20 ppm: meaty, brothy, roasted, metallic and nutty. |
Preparation Products |
2-[2-(4-Fluorophenyl)-2-oxo-1-phenylethyl]-4-methyl-3-oxo-N-phenylpentanamide |
Raw materials |
Lithium aluminium hydride-->THIOFORMAMIDE-->4-Methylthiazole |